自愈水凝胶
氨基酸
超分子化学
生物相容性
堆积
水溶液中的金属离子
化学
苯丙氨酸
配体(生物化学)
金属
盐(化学)
自组装
组合化学
高分子化学
有机化学
分子
生物化学
受体
作者
M.Z. Ma,Shi Qiu,Qiao Ye,Zhiyang Xu,Xiaoan Du,Ding Derui,Yi Yuan,Pengyao Xing,Wen-Qing Shang
标识
DOI:10.1002/slct.202301151
摘要
Abstract Natural amino acids are the most important building blocks in supramolecular chemistry which possess the best biocompatibility in nature. To the best of our knowledge, although hydrogels based on amino acid derivatives have already been studied widely, there is still no report about natural amino acids hydrogels constructed by metal ions induction method. Herein, the self‐assembly behaviors of twelve natural amino acids with eight metal ions were studied systematically. It is surprising that only sodium L‐Phenylalanine can self‐assemble into hydrogel with ZnCl 2 . Various methods were used to investigate the formation mechanism of hydrogel. The formation of hydrogel is triggered mainly via π‐π stacking and metal‐ligand interactions. Moreover, this green L‐Phenylalanine hydrogel displays acid responsiveness and relatively stability under high temperature, which has great potential applications in many fields.
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