Enhancing the sensitivity of a humidity sensor by using PVA and GQDs hybrid diaphragms and the harmonic Vernier effect

What we believe to be a novel fiber optic Fabry-Perot interferometer (FPI) humidity sensor based on polyvinyl alcohol (PVA) doped graphene quantum dots (GQDs) was proposed and experimentally studied. This sensor consisted of a sensing FPI and a reference FPI in parallel. The two sensing cavities FPI were composed of humidity sensitive materials PVA and PVA-GQDs, respectively. Experimental comparative studies had found that doping GQDs in PVA increases humidity sensitivity by 2.1 times. Four reference cavity FPIs were prepared by splicing single-mode fiber and quartz capillary, and then they were combined with two sensing cavity FPIs to form two Vernier effect (VE) sensors and two harmonic Vernier effect (HVE) sensors. Experimental research had found that the sensitivities of PVA as a sensing material for the VE sensor and HVE sensor were -1.0804 nm/%RH and-1.6566 nm/%RH, respectively. The sensitivities of PVA-GQDs as sensing materials for the VE sensor and HVE sensor were-3.1527 nm/%RH and 7.3343 nm/%RH, respectively. Moreover, both HVE sensors had minimal temperature crosstalk. PVA-GQDs were excellent humidity sensitive materials that significantly improve the sensitivity of humidity sensors, making it promising candidate for humidity sensing in various applications.