Microwave dielectric properties, vibrational spectrum, and antenna design of a novel melilite‐type Ba2CoSi2O7 ceramic

黄铁矿 陶瓷 微波食品加热 电介质 材料科学 介电常数 矿物学 化学 光电子学 电信 复合材料 冶金 尖晶石 计算机科学
作者
Z. Liu,Wei Wang,Diming Xu,Chao Du,Xin Wang,Guoqiang He,Fayaz Hussain,Tao Zhou,Biaobing Jin,Ke‐Hong Zhou,Jun Li,Chao Liang,Di Zhou
出处
期刊:Journal of the American Ceramic Society [Wiley]
卷期号:107 (12): 8342-8353
标识
DOI:10.1111/jace.20097
摘要

ABSTRACT Low‐ε r (the low dielectric constant) microwave dielectric ceramics play an important role in sub‐6 GHz band communication by virtue of their small signal delay. In this paper, Ba 2 CoSi 2 O 7 ceramics were synthesized by the solid‐phase reaction method, and X‐ray diffraction (XRD) confirms that they belong to a new melilite structure, with C 2/ c (No.15) space group, and the ceramics have good microwave dielectric properties with an ε r ∼ 7.37, a Q × f ( Q = 1/dielectric loss, f = resonant frequency) ∼ 26,320 GHz and a TCF (the temperature coefficient of resonant frequency) ∼ −55 ppm/°C after being sintered at 1150°C, and the theoretical dielectric constants derived from the Clausius–Mosotti as well as the porosity equation, respectively, are also used to further demonstrate the low‐ε r properties. Based on the group theory, the one‐dimensional integrable representations of Γ acoustic (the phonon modes) and Γ optical (optical modes) of Ba 2 CoSi 2 O 7 are obtained, and the internal vibrational modes of Ba 2 CoSi 2 O 7 are deconstructed and the main modes of influence of the electronic polarization are analyzed in conjunction with the results of the validly fitted peaks of the 17 Raman and 25 IR tests. A microstrip Yagi antenna is also designed based on the ceramic properties, which can achieve a gain of 9.65 dBi at the center tuning frequency of 5.47 GHz, with a S 11 (return loss) close to −60 dBi. Based on the above results, the Ba 2 CoSi 2 O 7 ceramic is a low‐ε r microwave dielectric ceramic with significant potential for communication application.
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