Metal-Free Decarboxylative C(sp3)-C(sp3) Bond Formation for the Synthesis of Unnatural Amino Acids and Peptides via Convergent Paired Electrolysis Enabled Radical-Radical Cross-Coupling

Herein, we present the first metal-free decarboxylative C(sp 3 )–C(sp 3 ) cross-coupling of glycine derivatives with redox-active esters through highly atom and energy economical convergent paired electrolysis enabled radical–radical cross-coupling.