环境化学
化学
碳纤维
荧光
腐殖质
环境科学
气溶胶
吸收(声学)
分析化学(期刊)
土壤水分
土壤科学
材料科学
物理
复合材料
有机化学
复合数
量子力学
作者
Yu Feng,Xiaofei Li,Rui Zhang,Jingning Guo,Wen Yang,Shichang Kang,Lang Liü,Yuqin Wang,Shichang Kang,Junji Cao
标识
DOI:10.1016/j.envpol.2023.121641
摘要
Brown carbon aerosols show obvious light absorption properties in the ultraviolet–visible (UV–Vis) range, which has an important impact on photochemistry and climate. In this study, experimental samples originated from the North slope of the Qinling Mountains (at two remote suburb sites) to study the optical properties of water-soluble brown carbon (WS–BrC) in PM2.5. The WS-BrC of TY (a sampling site on the edge of Tangyu of Mei county) has a stronger light absorption ability than CH (a rural sampling site, near the Cuihua Mountains scenic spot). The direct radiation effect of WS-BrC relative to elemental carbon (EC) is 6.67 ± 1.36% in TY and 24.13 ± 10.84% in CH in the UV range, respectively. In addition, two humic-like and one protein-like fluorophore components in WS-BrC were identified by fluorescence spectrum and parallel factor (EEMs-PARAFAC). Humification index (HIX), biological index (BIX) and fluorescence index (FI) together showed that the WS-BrC in the two sites may originate from fresh aerosol emissions. Potential source analysis of Positive Matrix Factorization (PMF) model show that the combustion process, vehicle, secondary formation and road dust are the main contributors to WS-BrC.
科研通智能强力驱动
Strongly Powered by AbleSci AI