差示扫描量热法
电介质
相变
化学
相(物质)
晶体结构
Crystal(编程语言)
结晶学
分析化学(期刊)
无机化学
材料科学
有机化学
热力学
物理
光电子学
计算机科学
程序设计语言
作者
Yu-Qing Wang,Yan Luo,Guan‐Cheng Xu
标识
DOI:10.1016/j.jssc.2023.124297
摘要
An In(III)-based organic-inorganic hybrid phase transition compound, (C4H9NH3)6[InCl6]Cl3 (1, C4H9NH3+ = isobutyl-ammonium cation) was synthesized. Differential scanning calorimetry (DSC) test reveals that 1 experiences a second-order phase transition at 193/199 K (Tc). Crystal structure analyses prove that the phase transition is associated with the displacement motion and structural distortion of isobutyl-ammonium cations. The temperature dependence of dielectric constant for 1 displays apparent step-like anomalies around the Tc, which makes it a potential dielectric response material. It is expected that this work will be beneficial to explore novel organic-inorganic hybrid compounds.
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