Nitrogen doped carbon layer of LiFePO4 improve the electrochemical performance for lithium ion batteries

Abstract In recent years, LiFePO 4 is considered as a promising cathode material for lithium-ion batteries. However, the low conductivity is a major disadvantage for this material. The nitrogen-doped carbon coated on the LiFePO 4 is an effective strategy to solve this drawback. Herein, we report a creative and facile method for fabricating nitrogen-doped carbon-coated LiFePO 4 (LFP/C-N) with sucrose and tripolycyanamide as carbon and nitrogen sources, respectively. As expected, the LFP coating with 1.25 wt% N decorating (LFP/C-N 1.25 ) exhibits a high specific capacities of 149.12 mAh g −1 at 1 C, better rate performance of 50.64 mAh g −1 at 10 C and favorable lithium ion diffusion coefficient of 2.15×10 -12 cm 2 s -1 . Therefore, we suggest that such novel LiFePO 4 material is a potential cathode material for lithium-ion batteries.