钙钛矿(结构)
材料科学
能量转换效率
非阻塞I/O
光伏系统
开路电压
钙钛矿太阳能电池
太阳能电池
短路
光电子学
溴化铵
晶体硅
电压
化学工程
化学
电气工程
工程类
肺表面活性物质
生物化学
催化作用
作者
Shammas Mushtaq,Sofia Tahir,Arslan Ashfaq,Ruy S. Bonilla,Muhammad Haneef,Rabia Saeed,Waqas Ahmad,Nasir Amin
出处
期刊:Solar Energy
[Elsevier]
日期:2023-01-01
卷期号:249: 401-413
被引量:37
标识
DOI:10.1016/j.solener.2022.11.050
摘要
Perovskites are at the forefront of research into potential alternatives for bulky and costly silicon-based solar cells. In recent years, lead-based organic and inorganic perovskite solar cells have broken efficiency records. However, these have stability issues and may pose health risks in the long-term. Hence, there has been ideally inorganic perovskite solar cells and parallel search for lead-free to match and eventually surpass the achievements of lead perovskite analogues. This study reports a modelling-guided device optimization process to design highly efficient lead-free n-i-p methyl ammonium tin bromide (MASnBr3) perovskite solar cells. We have studied the effect of the various hole and electron transport layers on the performance of MASnBr3 devices. The influence of different parameters, such as doping concentration of optimized HTLs/ETLs, the thickness of the perovskite layer, NA/ND of the absorption layer, and the defect density, is thoroughly investigated using numerical simulations. An optimized device FTO/SnO2/MASnBr3/NiO/Au is proposed here with an open circuit voltage of 1.1214 V, a short circuit current density of 34.8654 mA/cm2, fill factors of 88.30%, a theoretical power conversion efficiencies of 34.52%, and quantum efficiencies of 98%. This work reveals the potential of the MASnBr3 material as a perovskite for toxicity-free renewable energy.
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