富勒烯
材料科学
结构异构体
钙钛矿(结构)
光伏系统
锡
产量(工程)
纳米技术
光电子学
结晶学
有机化学
化学
复合材料
生态学
生物
冶金
作者
Chao Sun,Panpan Yang,Zi‐Ang Nan,Chengbo Tian,Yuanting Cai,Jingfu Chen,Fangfang Qi,Han‐Rui Tian,Liqiang Xie,Lingyi Meng,Zhanhua Wei
标识
DOI:10.1002/adma.202205603
摘要
Abstract Tin‐based perovskite solar cells (TPSCs) are attracting intense research interest due to their excellent optoelectric properties and eco‐friendly features. To further improve the device performance, developing new fullerene derivatives as electron transporter layers (ETLs) is highly demanded. Four well‐defined regioisomers (trans‐2, trans‐3, trans‐4, and e) of diethylmalonate‐C 60 bisadduct (DCBA) are isolated and well characterized. The well‐defined molecular structure enables us to investigate the real structure‐dependent effects on photovoltaic performance. It is found that the chemical structures of the regioisomers not only affect their energy levels, but also lead to significant differences in their molecular packings and interfacial contacts. As a result, the devices with trans‐2, trans‐3, trans‐4, and e as ETLs yield efficiencies of 11.69%, 14.58%, 12.59%, and 10.55%, respectively, which are higher than that of the as‐prepared DCBA‐based (10.28%) device. Notably, the trans‐3‐based device also demonstrates a certified efficiency of 14.30%, representing one of the best‐performing TPSCs.
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