Adsorption-based atmospheric water harvesting (AWH) with solar-driven photothermal desorption has become an effective means of solving freshwater scarcity in arid regions due to its low energy consumption and high efficiency. Moisture adsorption and desorption capacities are the most critical properties in AWH, and it is a challenge to improve the rate of moisture adsorption and desorption of composite adsorbents. Therefore, this paper reports a SA/carboxymethyl chitosan (CCS)/C/CaCl