Pt–Co Electrocatalysts: Syntheses, Morphologies, and Applications

Pt-Co electrocatalysts have attracted significant attention because of their excellent performance in many electrochemical reactions. This review focuses on Pt-Co electrocatalysts designed and prepared for electrocatalytic applications. First, the various synthetic methods and synthesis mechanisms are systematically summarized; typical examples and core synthesis parameters are discussed for regulating the morphology and structure. Then, starting with the design and structure-activity relationship of catalysts, the research progress of the morphologies and structures of Pt-Co electrocatalysts obtained based on various strategies, the structure-activity relationship between them, and their properties are summarized. In addition, the important electrocatalytic applications and mechanisms of Pt-Co catalysts, including electrocatalytic oxidation/reduction and bifunctional catalytic reactions, are described and summarized, and their high catalytic activities are discussed on the basis of their mechanism and active sites. Moreover, the advanced electrochemical in situ characterization techniques are summarized, and the challenges and direction concerning the development of high-performance Pt-Co catalysts in electrocatalysis are discussed.