One-pot preparation of magnetic nitrogen-doped porous carbon from lignin for efficient and selective adsorption of organic pollutants

Organic pollutants pose a serious threat to water environment, thus it is essential to develop high-performance adsorbent to remove them from wastewater. Herein, nitrogen-doped magnetic porous carbon (M-PLAC) with three-dimensional porous structure was synthesized from lignin to adsorb methylene blue (MB) and tetracycline (TC) in wastewater. The calculated equilibrium adsorption amount by M-PLAC for MB and TC was 645.52 and 1306.00 mg/g, respectively. The adsorption of MB and TC on M-PLAC conformed to the pseudo-second-order kinetic model. The removal of MB by M-PLAC showed fast and efficient characteristics and exhibited high selectivity for TC in a binary system. In addition, M-PLAC was suitable for a variety of complex water environments and had good regeneration performance, demonstrating potential advantages in practical wastewater treatment. The organic pollutant adsorption by M-PLAC was attributed to electrostatic interaction, hole filling effect, hydrogen bonding, and the π-π interaction.