环氧树脂
固化(化学)
材料科学
复合材料
高分子科学
高分子化学
作者
Junheng Zhang,Qinhua Qiu,Wei Yeat Yek,Feidi Wang,Zhixin Jia,Baochun Guo,Demin Jia
标识
DOI:10.1080/00914037.2011.593064
摘要
Abstract A new curing agent based on palmitoleic acid methyl ester modified amine (PAMEA) for epoxy resin was synthesized and characterized. Diglycidyl ether of bisphenol A (DGEBA) epoxy resins cured with different content of PAMEA along with diethylenetriamine (DETA) were prepared. The mechanical properties, dynamic mechanical properties, thermal properties, and morphology were investigated. The results indicated that the PAMEA curing agent can improve the impact strength of the cured epoxy resins considerably in comparison with the DETA curing agent, while the modulus and strength of the cured resin can also be improved slightly. When the PAMEA/epoxy resin weight ratio is 30/100, the comprehensive mechanical properties of the cured epoxy resin are optimal; at the same time, the crosslinking density and glass transition temperature of the cured epoxy resin are maximal. Keywords: curing agentepoxy resinmodified aminepalmitoleic acid methyl ester Acknowledgments This work was financially supported by the National Nature Science Foundation of China with grant number 51003031.
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