化学
脱质子化
螯合作用
席夫碱
吗啉
金属
立体化学
Atom(片上系统)
药物化学
结晶学
无机化学
离子
有机化学
计算机科学
嵌入式系统
作者
Nooraziah Mohd Lair,Hapipah Mohd Ali,Seik Weng Ng
标识
DOI:10.1107/s1600536809029171
摘要
The central Cd(II) atom in the trinuclear title compound, [Cd(3)(C(14)H(19)N(2)O(3))(2)(CH(3)COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octa-hedral geometry. Two of the acetate groups function in a μ(2)-bridging mode, while the other two each chelate to the terminal Cd(II) atom and simultaneously bind to the central metal atom in a κ(3)-bonding mode. The Schiff base anions N,O-chelate to the terminal metal atoms. The morpholine ring assumes a chair conformation.
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