超分子化学
超分子聚合物
聚合物
材料科学
纳米技术
金刚烷
分子动力学
非共价相互作用
分子
化学
计算化学
有机化学
氢键
复合材料
作者
Shideng Yuan,Anqi Guo,Heng Zhang,Zhining Wang,Shiling Yuan
标识
DOI:10.1021/acsami.3c15193
摘要
Supramolecular polymers offer promising potential for enhanced oil recovery (EOR) advancing techniques. Current instrumental analyses face limitations in capturing instantaneous intracomplex motions due to temporal and spatial constraints. The molecular mechanism of supramolecular polymer transport behavior within nanoconfinement is not yet fully understood. Therefore, the self-assembly mechanism of β-cyclodextrin (β-CD) and adamantane (ADA)-modified supramolecular polymers (p-AA-β-CD-ADA) was delved into in this work. Further exploration focuses on the translocation dynamics of p-AA-β-CD-ADA within nanoconfinement under external driving forces. Results suggest that β-CD and ADA in p-AA-β-CD-ADA were assembled into nodes in the form of a host and a guest, combining with a "node–rebar–cement" interaction model encapsulating the formation mechanism of these supramolecular polymers. The heightened density of the hydrate layers at the nanoscale pore throats acts as a constraining factor, resulting in restricted mobility and altered dynamics of the supramolecular polymers. During passage through nanopore throats, host–guest molecules within the supramolecular polymer experience noncovalent dissociation. Notably, these supramolecular polymers exhibit remarkable self-healing capabilities, reinstating their assembly state upon traversing pore throats. This work provides a molecular-level comprehension of the potential utility of supramolecular polymers in EOR processes, offering valuable information for the molecular design of polymers employed for EOR in low-permeability reservoirs.
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