Synthesis and Crystallization Mechanism for SAPO‐34 Zeolite Derived from Magadiite

In this work, we explored the hydrothermal synthesize and crystallization process of SAPO-34 zeolites from two-dimensional layered silicate magadiite by using tetraethylammonium hydroxide (TEAOH) as a templating agent. Comprehensive characterization was conducted by XRD, SEM, FTIR, Raman, and BET. Time-resolved PXRD analysis revealed that SAPO-34 zeolite exhibited a steep growth curve when the crystallization time was 30 h, and the crystallinity reached 98.65 % at 48 h. Specifically, the disruption of the magadiite layer exposed charged silanol groups on the surface, fostering an affinity for AlO