量子点
光致发光
材料科学
皮秒
硼
碳纤维
光电子学
飞秒
激发
发射光谱
激子
纳米技术
化学
物理
光学
谱线
凝聚态物理
激光器
有机化学
量子力学
天文
复合数
复合材料
作者
Weihua Li,Yuanyuan Han,Xiaohan Wang,Haiguang Zhao
出处
期刊:ACS applied nano materials
[American Chemical Society]
日期:2024-01-05
卷期号:7 (2): 2304-2311
标识
DOI:10.1021/acsanm.3c05760
摘要
Carbon dots (C-dots) have excellent optical properties and serve as optical building blocks for various potential applications. However, the origin of the double emission in C-dots is still unclear. It is highly desirable to understand deeply the exciton dynamics in double-emission C-dots on the picosecond time scale. Herein, for the first time, double-emission boron-doped carbon dots (B–C-dots) are synthesized with a quantum yield as high as 41.1%. The B–C-dots have an excitation-dependent quantum yield and photoluminescent spectrum. Compared to one dominant energy state in undoped C-dots, B–C-dots exhibited multiple energy states, as proved by femtosecond transient absorption spectroscopy. The controllable double emissions advance the design of a high-level anticounterfeiting code. As a proof-of-concept, by the combination of single-emission and double-emission C-dots, we produced a highly bright excitation-dependent photoluminescence code, showing the great potential for anticounterfeiting systems.
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