Tethered Trimeric Small‐molecular Acceptors through Aromatic‐core Engineering for Highly Efficient and Thermally Stable Polymer Solar Cells

Polymer solar cells (PSCs) rely on a blend of small molecular acceptors (SMAs) with polymer donors, where thermodynamic relaxation of SMAs poses critical concerns on operational stability. To tackle this issue, tethered SMAs, wherein multiple SMA-subunits are connected to the aromatic-core via flexible chains, are proposed. This design aims to an elevated glass transition temperature (T