Direct Recycling of Hot‐Deformed Nd–Fe–B Magnet Scrap by Field‐Assisted Sintering Technology

放电等离子烧结 磁铁 材料科学 废品 矫顽力 冶金 烧结 剩磁 粒子(生态学) 复合材料 磁化 磁场 合金 机械工程 凝聚态物理 海洋学 物理 量子力学 地质学 工程类
作者
Monica Keszler,Felix Großwendt,Anna-Caroline Assmann,Martin Krengel,Fernando Maccari,Oliver Gutfleisch,Doris Sebold,Olivier Guillon,Sebastian Weber,Martin Bram
出处
期刊:Advanced energy and sustainability research [Wiley]
卷期号:5 (1) 被引量:2
标识
DOI:10.1002/aesr.202300184
摘要

Recycling of Nd–Fe–B magnets is an ongoing challenge regarding circular economy. State‐of‐the‐art magnet production methods, such as hot deformation, have limitations with respect to direct recycling of magnet scrap particles that differ from pristine melt‐spun Nd–Fe–B powder. Recent work has shown that a combination of presintering by field‐assisted sintering technology/spark plasma sintering (FAST/SPS) and hot deformation by flash spark plasma sintering (flash SPS) has the potential to directly produce Nd–Fe–B magnets from 100% scrap material. Both processes have the capability to adjust and monitor process parameters closely, resulting in recycled magnets with properties similar to commercial magnets but made directly from crushed and recycled Nd–Fe–B powder that partially or completely replaces pristine melt‐spun Nd–Fe–B powder. Herein, a systematic study is done inserting recycled magnet particles into a flash SPS deformed magnet, considering the effects of different weight percentages of scrap material of varied particle size fractions. In some cases, coercivity H cJ of >1400 kAm −1 and remanence B r of 1.1 T can be achieved with 20 wt% scrap material. The relationship between particle size fraction, oxygen uptake, and percentage of recyclate in a final magnet are all explored and discussed with respect to magnets made from pristine material.
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