Flexible Self‐Powered Energy Systems Based on H2O/Ni2+ Intercalated NixV2O5 ⋅ nH2O

Abstract The development of portable electronic devices has created greater demands for multifunctional energy integration systems. Self‐powered systems have gained widespread interest because they can collect and storage renewable environmental energy and provide stable electricity to electronic devices. Herein, we developed a flexible self‐charging energy system, involving textile‐based zinc‐ion hybrid (ZIHC) and triboelectric nanogenerator (TENG), which demonstrates wearable, compatibility, lightweight and can quickly harvest and store energy. Ni x V 2 O 5 ⋅ n H 2 O (NVO) loaded on carbon cloth (CC) with Ni 2+ /H 2 O ions intercalated as the cathode was assembled with activated CC to form a ZIHC, which has a voltage range of 2.0 V and capacitance value of 267.1 mF cm −2 as well as good charge and discharge rates and excellent cycling stability. At the same time, the NVO/CC can be assembled with PDMS to form a TENG achieving a maximum instantaneous power of 18.5 mW cm −2 . The device can be flexibly worn over the body to continuously harvest and store biomechanical energy and charge the electronic wristwatch successfully. This work demonstrates great convenience and promising practical applications as sustainable flexible energy system for portable electronic devices.