Structural and Reactivity Insights into High-Valent Co(III)-(μ-peroxo)-Co(IV) and Its Electromer Co(III)-(μ-superoxo)-Co(III)

Various metalloenzymes employ O 2 for oxidative reactions, which is crucial in catalysis and biological processes involving high-valent metal-oxygen species. This study introduces novel high-valent Co(III)-(μ-1,2-O 2 )-Co(IV) and Co(III)-(μ-1,2-O 2 ●– )-Co(III) complexes, stabilized by...