材料科学
环氧树脂
氧化铈
盐雾试验
涂层
氧化物
介电谱
富马酸
腐蚀
铈
化学工程
对苯二甲酸
核化学
表面改性
盐(化学)
复合材料
电化学
冶金
有机化学
化学
聚酯纤维
电极
物理化学
工程类
作者
Yinxia Dong,Yingjun Zhang,Xuejun Cui,Ming‐Tian Li,Chun Xie,Zhongwen Pan
出处
期刊:Anti-corrosion Methods and Materials
[Emerald (MCB UP)]
日期:2023-04-26
卷期号:70 (4): 149-156
被引量:6
标识
DOI:10.1108/acmm-02-2023-2762
摘要
Purpose The study aims to investigate the anticorrosion performance of epoxy coatings using modified cerium oxide (CeO 2 ) by terephthalic acid (CeO 2 -t) and fumaric acid (CeO 2 -f) as corrosion inhibitors. Design/methodology/approach The chemical state of CeO 2 -t, and CeO 2 -f were analyzed by infrared radiation (IR) and X-ray diffraction (XRD). The effect of different inhibitors on the coating properties was analyzed by neutral salt spray tests (NSST) and electrochemical impedance spectroscopy (EIS). Findings The results of IR and XRD illustrate that the modification of CeO 2 was successful, and fumaric acid underwent a ring-opening reaction with epoxy resin (EP) in the coatings. The results of NSST and EIS showed that the coatings containing CeO 2 -f exhibited the best anticorrosion performance. Originality/value CeO 2 is an effective inhibitor of the organic coatings. When surface modified, it is chemically bonded to EP, enhancing the anticorrosion performance of EP.
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