Cutting‐Edge Progress in Aqueous Zn‐S Batteries: Innovations in Cathodes, Electrolytes, and Mediators

Abstract Rechargeable aqueous zinc‐sulfur batteries (AZSBs) are emerging as prominent candidates for next‐generation energy storage devices owing to their affordability, non‐toxicity, environmental friendliness, non‐flammability, and use of earth‐abundant electrodes and aqueous electrolytes. However, AZSBs currently face challenges in achieving satisfied electrochemical performance due to slow kinetic reactions and limited stability. Therefore, further research and improvement efforts are crucial for advancing AZSBs technology. In this comprehensive review, it is delved into the primary mechanisms governing AZSBs, assess recent advancements in the field, and analyse pivotal modifications made to electrodes and electrolytes to enhance AZSBs performance. This includes the development of novel host materials for sulfur (S) cathodes, which are capable of supporting higher S loading capacities and the refinement of electrolyte compositions to improve ionic conductivity and stability. Moreover, the potential applications of AZSBs across various energy platforms and evaluate their market viability based on recent scholarly contributions is explored. By doing so, this review provides a visionary outlook on future research directions for AZSBs, driving continuous advancements in stable AZSBs technology and deepening the understanding of their charge–discharge dynamics. The insights presented in this review signify a significant step toward a sustainable energy future powered by renewable sources.