In situ transformation boosts the pseudocapacitance of CuNi-MOF via cooperative orientational and electronic governing

The disordered arrangement and thereof inferior conductivity of 2D MOF sheets seriously hinder their practical application. Herein, we propose in situ transformation strategy to architect vertically oriented bimetallic CuNi-MOF as a self-supporting electrode, leading to a decuple high specific capacitance of 1262 C g-1 in comparison with the pristine Ni-MOF powder of 114 C g-1 at 2 A g-1. DFT calculations reveal that introduction of Cu can modulate the electronic structure of metal centers in the Ni-MOF sheets and optimize electrical conductivity. Our strategy is promising to maximize the utilization of MOF superiorities for optimizing their electrochemical performance.