环氧树脂
热固性聚合物
缩水甘油醚
双酚A
碳化
材料科学
固化(化学)
烧焦
吸附
阻燃剂
化学工程
复合材料
热解
化学
有机化学
工程类
作者
Hafezeh Nabipour,Xin Wang,Limin Song,Yuan Hu
标识
DOI:10.1016/j.mtsust.2022.100265
摘要
The production of multifunctional carbon foams from biomass has attracted great interest due to the increasing awareness of green and sustainable development. Here, we report a bio-based epoxy thermoset prepared by curing a furan-derived di-functional epoxy monomer (5-hydroxymethyl-2-furaldehyde (HMF)-3, 5-diamino-1,2,4-triazole (GU)-EP) with a furan-derived curing agent, 5,5′-methylenedifurfurylamine (DFA). For comparison, the cured commercial diglycidyl ether of bisphenol-A was used as a thermoset epoxy resin. Due to its unique structure rich in aromatic and nitrogenous structures, the cured HMF-GU-EP/DFA thermoset possessed exceptional charring ability. This fully bio-based epoxy thermoset had a very high char yield (55.8 wt%) at 800 °C under nitrogen, while the cured diglycidyl ether of bisphenol-A/4, 4′-diaminodiphenylmethane was only 13.6 wt%. Due to this excellent carbonization ability, the cured HMF-GU-EP/DFA was carbonized at 700 °C to obtain a carbon foam as a CO2 absorbent. The Brunauer–Emmett–Teller surface area and total pore volume were measured to be 472 m2/g and 0.22 cm3/g, respectively. The amounts of CO2 adsorbed with this carbon foam were 4.72 and 2.15 mmol/g at 273 and 298 K, respectively. In conclusion, this study provides a bio-based, strong and rigid, inherently flammable, and highly carbonizable epoxy thermoset and the potential application of its carbonized foam as an efficient adsorbent for CO2 capture.
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