Influence of synthesis routes on the performance of Ni nano-sized catalyst supported on CeO2-Al2O3 in the dry reforming of methane

Abstract The dry reforming of methane is a potential solution to mitigate the global warming effect. In this study, the effects of various preparation methods including the impregnation, coprecipitation, and combined coprecipitation-impregnation on physical characteristics and DRM catalytic performance of Ni-CeO 2 -Al 2 O 3 were investigated. The synthetic procedure was discovered to have a crucial role in the basicity and reducibility, as well as nickel dispersion of catalyst. With affordable basicity and high reducibility, the combination of coprecipitation-impregnation exhibited the best performance with CH 4 and CO 2 steady-state conversions of 72% and 82%, respectively. Moreover, the deactivation of catalysts was also studied. The formation of low graphitic type showed less harmful to catalyst.