Low‐Cost, Large‐Area, and Highly Transparent Organic Glassy Scintillators for High Resolution X‐Ray Imaging

Abstract The architectural design and fabrication of low‐cost, high‐performance organic scintillators are critical for medical imaging and material/device analysis. However, achieving large‐area and high‐transparency organic scintillators in a low‐cost and easy‐to‐implement method remains a challenge. Herein, a new design strategy for regulating the side chain length of maleimide derivatives is demonstrated to develop organic scintillators for achieving low‐cost, large‐area, and high spatial resolution in X‐ray imaging. The effective intermolecular interactions and relatively twisted molecular structure endow PAM‐M4 molecule with outstanding scintillator properties. More importantly, as demonstrated for the first time, pure organic glassy films with a diameter over 10 cm and high optical transparency can be prepared by the developed melt‐quenched method using PAM‐M4 crystal powder as a raw material. This glassy film exhibits excellent X‐ray imaging ability with a spatial resolution as high as 27.0 lp mm −1 at MTF = 0.20, which is one of the best results among reported organic scintillators. The results of this work not only develop a new design strategy for high‐performance organic scintillators but also demonstrate a reliable approach to fabricating large area screens with superior spatial resolution for medical or industrial X‐ray imaging applications.