化学
镍
卤化物
催化作用
芳基
电催化剂
激进的
电化学
碳纤维
光化学
配对
组合化学
无机化学
有机化学
电极
物理
复合数
物理化学
复合材料
量子力学
超导电性
材料科学
烷基
作者
P. Xue,Liubo Li,Niankai Fu
出处
期刊:Organic Letters
[American Chemical Society]
日期:2022-10-06
卷期号:24 (41): 7595-7599
被引量:19
标识
DOI:10.1021/acs.orglett.2c03034
摘要
We report an electrocatalytic approach for esterification of aryl halides by pairing iron and nickel electrocatalysis. The reaction involves anodically iron-catalyzed oxidation of carbazates to produce alkoxycarbonyl radicals. The carbon-centered radicals then enter nickel catalysis that is powered by cathodic reduction to deliver the radical coupling products. Mechanistic data are consistent with arylnickel(II) species as the key intermediates enabling the desired carbon–carbon bond formation.
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