三吡啶
过电位
锰
乙腈
化学
电化学
羧酸盐
氢键
无机化学
立体化学
电极
有机化学
分子
物理化学
金属
作者
Qianqian Wu,Minghong Li,Shuanglin He,Ying Xiong,Ping Zhang,Heyan Huang,Lin Chen,Fang Huang,Fei Li
摘要
The manganese terpyridine complex 1 with a coordinated carboxylate in the axial position was obtained in situ. By virtue of a hangman effect, complex 1 catalyzes electrochemical hydrogen evolution from phenol in acetonitrile solution with a turnover frequency of 525 s-1 at a low overpotential of ca. 230 mV.
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