过电位
材料科学
阳极
锌
磁场
成核
极化(电化学)
电化学
电极
电解质
电场
饱和(图论)
枝晶(数学)
洛伦兹力
传质
化学工程
化学物理
冶金
机械
热力学
化学
物理
量子力学
组合数学
工程类
物理化学
数学
几何学
作者
Qiang Chen,Chenhao Jiang,Maolin Chen,Jianli Zhang,Guangya Hou,Yiping Tang
标识
DOI:10.1016/j.surfin.2022.101972
摘要
Zinc-based batteries have high theoretical specific capacity and low production cost, but the formation of Zn dendrites limits its practical application in aqueous batteries. In this work, a new method for Zn dendrite suppression by external magnetic field is proposed. Under the interaction of magnetic field and electric field, Zn ions are affected by Lorentz force and spiral motion, which produces disturbance to the electrolyte and promotes the mass transfer process on the electrode surface. This process promotes the mass transfer process on the electrode surface, makes the distribution of zinc ions more uniform, reduces the concentration polarization, and effectively inhibits the growth of zinc dendrites. The electrochemical performance test results show that the magnetic field effect can effectively reduce the nucleation overpotential of Zn and prolong the cycle life. This new method of Zn dendrite suppression by applying magnetic field to the outside of the cell without modifying the inside of the cell has a very wide range of research and application value.
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