催化作用
过电位
单原子离子
材料科学
碳纤维
密度泛函理论
过渡金属
无定形碳
Atom(片上系统)
分解水
碳纳米管
纳米技术
无定形固体
化学工程
化学
物理化学
结晶学
计算化学
有机化学
复合材料
电化学
嵌入式系统
工程类
复合数
光催化
计算机科学
电极
作者
Chunxiang Liu,Ganghuo Pan,Nianjie Liang,Song Hong,Jingyuan Ma,Yuzhou Liu
标识
DOI:10.1002/advs.202105392
摘要
The research of high efficiency water splitting catalyst is important for the development of renewable energy economy. Here, the progress in the preparation of high efficiency hydrogen evolution reaction (HER) catalyst is reported. The support material is based on a polyhexaphenylbenzene material with intrinsic holes, which heals into carbon materials upon heating. The healing process is found to be useful for anchoring various transition metal atoms, among which the supported Ir Single-atom catalyst (SAC) catalyst shows much higher electrocatalytic activity and stability than the commercial Pt/C and Ir/C in HER. There is only 17 mV overpotential at 10 mA cm
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