Identifying sources and transport routes of heavy metals in soil with different land uses around a smelting site by GIS based PCA and PMF

Identifying sources and transport routes of heavy metals in soil is necessary for pollution control. This study integrated principal component analysis (PCA), positive matrix factorization (PMF), and geographic information system (GIS) mapping to identify the sources, transport routes, and apportion heavy metals in soil based on land uses around a smelting site. The results revealed that the mean concentrations of As, Hg, Cd, Pb, Zn, and Cu in the soil exceeded their background values except for Cr, Mn, and Fe, which were slightly higher. According to the mean Igeo values, the soils were most polluted with As, Cd, Pb, and Cu, followed a decreasing order of grassland (1.71, 2.38, 2.10, and 1.73) > agricultural land (0.632, 2.32, 1.19, and 1.08) > forestland (0.255, 0.952, 0.654, and 0.148). Smelter emissions and soil parent materials were the primary sources of heavy metals. The PCA and PMF factor hotspots visualized by GIS were mostly distributed within the smelting site, slag and wastewater runoff areas, and in the dominant wind direction. The GIS based PCA and PMF results confirmed that As, Cd, Pb, Cu, and Zn were transported mainly by surface runoff and atmospheric deposition, while Hg was mostly from atmospheric deposition. Grassland and agricultural land soils received heavy metals from surface runoff and atmospheric deposition, while forestland soils only received from atmospheric deposition. The integrated approach was useful in identifying the sources, transport routes, and contributions of the heavy metals among different land uses, thereby assisting policymakers in understanding the sources and transport routes of heavy metals in the soil around smelting areas.