硼
替代(逻辑)
化学
Atom(片上系统)
组合化学
配体(生物化学)
光化学
纳米技术
有机化学
材料科学
计算机科学
生物化学
受体
嵌入式系统
程序设计语言
作者
Rosinah Liandrah Gapare,Alison Thompson
摘要
Recent synthetic achievements have led to 4,4-disubstituted-4-bora-3a,4a-diaza-s-indacenes (BODIPYs) with varying substituents at the meso, pyrrolic and/or boron sites, with each influencing photophysical properties and utility. This Feature article gives an overview of chemistry at the boron atom in BODIPYs, highlighting our contributions that evolved from synthetic curiosities and now offer this dipyrrolic skeleton potential across a wider range of applications. We first summarise preparative routes to BODIPYs through complexation of boron with the dipyrrinato ligand. The role of boron in protecting dipyrrins is then discussed, followed by strategies by which to achieve facile substitution at the boron atom.
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