催化作用
化学
矿化(土壤科学)
硝基苯
阴极
渗滤液
化学工程
碳纤维
材料科学
环境化学
有机化学
复合数
工程类
物理化学
复合材料
氮气
作者
Xu Yang,Zhimin Chen,Shichao Du,Huiyuan Meng,Zhiyu Ren
出处
期刊:Chemosphere
[Elsevier]
日期:2022-04-01
卷期号:293: 133532-133532
被引量:22
标识
DOI:10.1016/j.chemosphere.2022.133532
摘要
The electro-Fenton oxidation is one of the powerful approaches for achieving the complete mineralization of organic pollutants in water. The key dilemma for efficient industrial application of electro-Fenton oxidation is the complicated post-processing of iron sludge, and the cost and risk associated with H2O2 transportation and storage. Herein, Cu-coupled Fe/Fe3C covered with carbon layer on carbon felt (Cu-Fe/Fe3C@C), engineered by a hydrothermal reaction followed by the consequent thermal-treatment in N2 atmosphere, as a self-supported integrated cathode were used for an onsite oxygen reduction reaction and a Fenton oxidation reaction. Experimental evidences demonstrate that, at the operating potential of -1.1 V, Fe3C can selectively catalyze O2 into H2O2 by 2e reduction pathways with assistance of metal Cu. Meanwhile, metal Fe and Cu incorporated into Cu-Fe/Fe3C@C simultaneously motivate the onsite Fenton oxidation arose by H2O2. Such a win-win catalyst presented high activity in the electro-Fenton process. In acidic environment, the efficient mineralization rate of methylene blue, nitrobenzene, phenol, and bisphenol A can reach more than 70% in 60 min, as well as the excellent stability and durability due to the protection of graphited carbon layer. Compared with tradition electrochemical degrade system, the prepared Cu-Fe/Fe3C@C electrode as cathode for practical refractory brewing leachate treatment reveal more efficient decolorization and mineralization, saving 14.3% of electricity.
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