材料科学
吸附
催化作用
化学工程
异质结
电化学
过电位
塔菲尔方程
电极
化学
光电子学
生物化学
工程类
物理化学
有机化学
作者
Hui Zong,Chaoqun Shang,Shijing Gong,Ke Yu,Z. Q. Zhu
标识
DOI:10.1016/j.electacta.2021.139781
摘要
Efficient catalysts designed by reasonable heterostructure engineering have a bright prospect for lithium-sulfur batteries (LSBs) and hydrogen evolution reaction (HER). Here, we determined Nb2C MXene and MoS2 to form heterojunction due to their high lattice adaptation. The unique flower-petal-like Nb2C MXene was prepared by freeze-drying, the MoS2 growing on the surface of Nb2C MXene by hydrothermal method. We applied the MoS2/Nb2C hybrids to LSB for the first time. The MoS2/Nb2C hybrids showed a specific capacity of 919.2 mAh g−1 at 0.2 C after 200 cycles with excellent retention of 92.2% when used as the cathode of LSBs. The MoS2/Nb2C electrode was used for HER under alkaline condition, which showed a Tafel slope of 65.1 mV dec−1, an overpotential of 117 mV at 10 mA cm−2 and excellent long-term robustness of HER performance. The mechanism of excellent properties of LSBs and HER activity were explained from the perspective of adsorption energy calculated according to the first principles. The adsorption activity of the MoS2/Nb2C heterojunction is much higher than that of bare MoS2 from the point of view of lithium polysulfides (LiPS) and hydrogen atoms. The heterostructure engineering of the MoS2/Nb2C hybrids is of guiding significance for green energy and energy conversion.
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