硫酚
光催化
邻苯二甲酰亚胺
化学
可见光谱
光催化
光化学
催化作用
胺化
组合化学
邻苯二甲酰亚胺
腙
有机化学
光电子学
材料科学
作者
Yunhe Jin,Haijun Yang,Hua Fu
出处
期刊:Organic Letters
[American Chemical Society]
日期:2016-12-07
卷期号:18 (24): 6400-6403
被引量:84
标识
DOI:10.1021/acs.orglett.6b03300
摘要
We have developed visible-light photoredox decarboxylative couplings of N-(acetoxy)phthalimides without an added photocatalyst in which simple and commercially available thiophenols are used as the effective organocatalysts, and 4-(trifluoromethyl)thiophenol shows optimal catalytic activity. Three representative decarboxylative examples were chosen including one amination and two C–C bond couplings to confirm efficacy of the visible-light photoredox reactions, and the results exhibited that they performed very well at room temperature. The interesting discovery should provide a novel and environmentally friendly strategy for visible-light photoredox transformation of organic molecules.
科研通智能强力驱动
Strongly Powered by AbleSci AI