聚吡咯
石墨烯
材料科学
介电谱
傅里叶变换红外光谱
循环伏安法
衰减全反射
X射线光电子能谱
扫描电子显微镜
氧化物
化学工程
分析化学(期刊)
兴奋剂
电化学
纳米技术
复合材料
化学
电极
有机化学
物理化学
聚合物
光电子学
工程类
冶金
聚合
作者
J. Molina,Andréa Zille,J. Fernández,A. Pedro Souto,J. Bonastre,F. Cases
标识
DOI:10.1016/j.synthmet.2015.03.014
摘要
Polyester (PES) has been coated with polypyrrole (PPy) to produce conducting fabrics. Graphene oxide (GO) has been used in different concentrations (10, 20 and 30% weight) as counter ion to neutralize the positive charges of the PPy structure. Fourier transform infrared spectroscopy with attenuated total reflection (FTIR-ATR), energy dispersive X-ray (EDX) and X-ray photoelectron spectroscopy (XPS) of the PPy/GO powders corroborated the incorporation of GO as counter ion due to the presence of O in the EDX spectrum, as well as an excess of C, arising from GO contribution. The doping level (N+/N) decreased with the GO content. Field emission scanning electron microscopy (FESEM) showed the formation of the PPy/GO coating and the incorporation of GO in the composite. Electrochemical impedance spectroscopy (EIS) in solid state and solution, cyclic voltammetry (CV) and scanning electrochemical microscopy (SECM) were used to test the electrical properties and electroactivity of the fabrics. There was a decrease in the electrical properties and electroactivity as the GO content increased. The conductivity of the fabrics could be tuned by varying the GO content.
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