材料科学
表面粗糙度
表面张力
弹性模量
电解质
聚合物
复合材料
电极
热力学
化学
物理化学
物理
作者
Charles W. Monroe,John Newman
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2005-01-01
卷期号:152 (2): A396-A396
被引量:1404
摘要
Past theories of electrode stability assume that the surface tension resists the amplification of surface roughness at cathodes and show that instability at lithium/liquid interfaces cannot be prevented by surface forces alone [Electrochim. Acta, 40, 599 (1995)]. This work treats interfacial stability in lithium/polymer systems where the electrolyte is solid. Linear elasticity theory is employed to compute the additional effect of bulk mechanical forces on electrode stability. The lithium and polymer are treated as Hookean elastic materials, characterized by their shear moduli and Poisson's ratios. Two-dimensional displacement distributions that satisfy force balances across a periodically deforming interface are derived; these allow computation of the stress and surface-tension forces. The incorporation of elastic effects into a kinetic model demonstrates regimes of electrolyte mechanical properties where amplification of surface roughness can be inhibited. For a polymer material with Poisson's ratio similar to poly(ethylene oxide), interfacial roughening is mechanically suppressed when the separator shear modulus is about twice that of lithium. © 2005 The Electrochemical Society. All rights reserved.
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