聚丙烯
材料科学
聚合物
高分子科学
聚烯烃
催化作用
茂金属
复合材料
工艺工程
有机化学
聚合
化学
工程类
图层(电子)
作者
Gabriele Mei,Enrico Beccarini,Tiziana Caputo,Cornelia Fritze,Paola Massari,Dania Agnoletto,Silvio Pitteri
标识
DOI:10.1177/8756087909343500
摘要
The Spherizone process technology, which is based on a multizone circulating reactor (MZCR), represents a significant innovation in polypropylene (PP) production. In comparison to traditional multi-step technologies, the MZCR provides a step change in the polymer homogeneity of the final product, obtained by continuously circulating the growing polymeric granules between two interrelated zones where different gas-phase compositions are realized. In addition to traditional Z-N catalysts, metallocene catalysts are also being introduced in PP manufacture: single-site catalysts allow differentiated products with outstanding property combinations. Due to its versatility and sustainability, PP continues to be utilized in a large range of applications. Innovative polymer structures featuring diverse comonomers exhibit improved properties (i.e., stiffness-impact balance, aesthetics, transparency, processability), which reinforce the capability of PP to replace traditional materials such as wood, paper, glass, and metals, as well as standard polymer products.
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