吡啶
菲咯啉
红外光谱学
结晶学
化学
晶体结构
配体(生物化学)
单晶
热分析
离子
红外线的
光谱学
无机化学
热的
药物化学
有机化学
生物化学
物理
受体
气象学
量子力学
光学
作者
Xin Hu,Jixi Guo,Yongjiang Wang,Cong Liu
标识
DOI:10.1016/j.saa.2009.04.027
摘要
A new pyridine-2,6-dicarboxylate iron(III)/iron(II) complex [Fe(phen)(3)][Fe(2)(PDC)(4)].3CH(3)OH was synthesized and characterized (where PDC=pyridine-2,6-dicarboxylate, phen=1,10-phenanthroline) by using elemental analysis, IR spectroscopy and thermal analyses (TGA and DTA). The molecular structure of the complex has been determined by single-crystal X-ray diffraction. The complex is mixed-ligands and the IR spectra display bands characteristic of coordinated mixed-ligand bases. All the IR results are in agreement with the X-ray crystal result. The bond lengths indicate that this complex has [Fe(phen)(3)](2+) cation where Fe(II) ion is in typical low-spin state, and in counter ions, [Fe(PDC)(2)](-) are both in high-spin state.
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