Effect of surfactants on the transport of polyethylene and polypropylene microplastics in porous media

微塑料 肺表面活性物质 化学工程 十二烷基苯磺酸钠 化学 离子强度 多孔介质 Zeta电位 色谱法 环境化学 多孔性 有机化学 水溶液 纳米颗粒 工程类
作者
Yanji Jiang,Xianqiang Yin,Xianglong Xi,Duo Guan,Huimin Sun,Nong Wang
出处
期刊:Water Research [Elsevier]
卷期号:196: 117016-117016 被引量:133
标识
DOI:10.1016/j.watres.2021.117016
摘要

The transport of microplastics in porous media is attracting increasing attention. However, to date, research is limited to polystyrene microplastics. Meanwhile, surfactants can promote solid dispersion to form a stable suspension, possibly allowing microplastics to migrate when attached to a surfactant, which would increase the scope and degree of microplastic pollution, further endangering human health and the stability of the ecological environment. Therefore, in this study, the transport behavior of microplastics in porous media was explored in the presence of surfactants. Herein, polyethylene (PE) and polypropylene (PP) were evaluated while dispersed by two ionic surfactants: cationic surfactant-cetyltrimethylammonium bromide (CTAB) and anionic surfactant-sodium dodecylbenzenesulfonate (SDBS). The influence of different factors (surfactant concentration, ionic strength, pH, flow rate, and multivalent cations) on the transport of microplastics in porous media was explored via quartz sand packed-column experiments. Our experimental results show that the transport abilities of PE and PP increased with increasing surfactant concentration when the surfactant concentration was less than the critical micelle concentration (CMC). In the presence of CTAB and SDBS, physicochemical factors had different effects on the transport of microplastics mainly by controlling Zeta potential, advection diffusion and CMC. The mobility of PE and PP decreased with increasing ionic strength, cation valence and pH, and decreasing flow rate. However, the mobility of PE and PP under CTAB is much greater than that of PE and PP under SDBS, because quartz sand can absorb more CTAB molecules through electrostatic attraction to weaken the collision between microplastics and quartz sand. Further, the transport ability of PP was greater than that of PE under all conditions considered. Notably, the Extended-Derjaguin-Landau-Verwey-Overbeek (XDLVO) theory formed by adding osmotic, elastic, and hydrophobic force could well described the migration behavior of microplastics in CTAB and SDBS well. This research highlights that surfactant has a significant impact on the transport ability of microplastics, and provides a comprehensive understanding of the migration and fate behaviors of microplastics affected by surfactants, which is necessary to prevent and reduce the environmental hazards of microplastics.
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