迷惑
限制电流
电极
氧气输送
体积流量
电化学
质子交换膜燃料电池
材料科学
多孔性
化学工程
化学
机械
氧气
复合材料
燃料电池
工程类
物理
有机化学
物理化学
作者
Xiaodong Wang,Yuanyuan Duan,Wei‐Mon Yan
标识
DOI:10.1016/j.jpowsour.2007.08.037
摘要
An appropriate flow field in the bipolar plates of a fuel cell can effectively enhance the reactant transport rates and liquid water removal efficiency, improving cell performance. This paper proposes a novel serpentine-baffle flow field (SBFF) design to improve the cell performance compared to that for a conventional serpentine flow field (SFF). A three-dimensional model is used to analyze the reactant and product transport and the electrochemical reactions in the cell. The results show that at high operating voltages, the conventional design and the baffled design have the same performance, because the electrochemical rate is low and only a small amount of oxygen is consumed, so the oxygen transport rates for both designs are sufficient to maintain the reaction rates. However, at low operating voltages, the baffled design shows better performance than the conventional design. Analyses of the local transport phenomena in the cell indicate that the baffled design induces larger pressure differences between adjacent flow channels over the entire electrode surface than does the conventional design, enhancing under-rib convection through the electrode porous layer. The under-rib convection increases the mass transport rates of the reactants and products to and from the catalyst layer and reduces the amount of liquid water trapped in the porous electrode. The baffled design increases the limiting current density and improves the cell performance relative to conventional design.
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