吸附
磷酸盐
齿合度
选择性
表面改性
反应性(心理学)
X射线光电子能谱
化学
插层(化学)
化学工程
无机化学
金属
有机化学
物理化学
催化作用
工程类
替代医学
病理
医学
作者
Meiqi Li,Yi Mu,Hai Shang,Chengliang Mao,Shiyu Cao,Zhihui Ai,Lizhi Zhang
标识
DOI:10.1016/j.apcatb.2019.118364
摘要
In this study, we demonstrate that surface phosphate modification of nZVI (p-nZVI) could enhance the electron selectivity of Cr(VI) reduction from 6.1% to 31.3%, as estimated by XANES and XPS, and thus promote the Cr(VI) removal efficiency by 4 folds. DFT calculation and experimental results revealed that phosphate groups were adsorbed on the surface of p-nZVI via a monodentate mononuclear model to inhibit the reaction with oxygen and/or water via the pendant protons of phosphate, accounting for high electron selectivity of p-nZVI. More importantly, surface phosphate modification shifted the binding configuration of Cr(VI) from a monodentate mononuclear model on nZVI to bidentate binuclear one on the p-nZVI surface, thus strengthening the Cr(VI) adsorption ability and favoring the subsequent Cr(VI) reduction. This study provides a facile strategy to enhance the electron selectivity towards metal remediation, and highlights the vital influence of surface structure on nZVI reactivity at the molecular level.
科研通智能强力驱动
Strongly Powered by AbleSci AI