材料科学
蔗渣
碳纤维
化学工程
煅烧
热解
锂(药物)
复合数
复合材料
制浆造纸工业
化学
催化作用
有机化学
医学
内分泌学
工程类
作者
Huiting Ai,Wei Li,Zheng Liu,Dan Sun,Hanzi Zhou,Guo‐Cheng Han
标识
DOI:10.1016/j.jallcom.2020.157156
摘要
A cathode material carbon-coated Na2FePO4F (Na2FePO4[email protected]) was reported which were derivated from waste biomass bagasse as carbon source were prepared by wet ball milling and in-situ pyrolysis, due to the low cost and easy availability of biomass carbon materials. The performance results shown that the Na2FePO4[email protected] composite material prepared under the condition of 10% carbon source and calcination temperature of 650 °C crystallized well, and the carbon material was coated on the external of Na2FePO4F well with no damaging the crystal structure of the material. The first ring discharging specific capacity with Na2FePO4[email protected] was 128 mA h g−1 based on 0.1 C current density, which was a three-fold increase compared with the carbon-free coated material Na2FePO4F (40 mA h g−1). The coulomb efficiency of Na2FePO4[email protected] cathode material remained above 97.8% after 30 cycles at 0.1 C. This work applied biomass carbon materials to hybrid ion batteries, offering more possibilities for the development of sodium-based fluorophosphate materials for lithium-ion batteries coated with low-cost biomass-based carbon materials.
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