磁铁矿
高分辨率透射电子显微镜
结构精修
X射线光电子能谱
材料科学
分析化学(期刊)
氧烷
扩展X射线吸收精细结构
微晶
阳极
纳米颗粒
吸收光谱法
化学
结晶学
透射电子显微镜
化学工程
光谱学
物理化学
晶体结构
纳米技术
物理
色谱法
量子力学
工程类
电极
冶金
作者
Sameh I. Ahmed,Moustafa M.S. Sanad
标识
DOI:10.1016/j.jallcom.2020.157962
摘要
Anode materials for Lithium-Ion Batteries (LIBs) based on Mo- and V-doped maghemite were prepared by the sol-gel route. High-Resolution Transmission Electron Microscopy (HRTEM) showed the formation of isotropic nanoparticles. The X-ray Photoelectron Spectroscopy (XPS) revealed the presence of Fe3+ and Mo6+ or V4+ for Mo- or V-doped samples, respectively. Rietveld refinement of X-ray Diffraction (XRD) patterns revealed the distribution of Mo6+ and V4+ cations and showed increase in vacancies. The crystallite size resulted from Rietveld adjustments was in agreement with the HRTEM results. The Extended X-ray Absorption Fine Structure (EXAFS) showed a shrinkage of Fe–O–Fe linkages which is responsible for the reduction of the maghemite cell parameter which agreed with the structural analysis from XRD. The X-ray Absorption Near Edge Structure (XANES) confirmed XPS analysis that Fe3+ is present. Coin cells were assembled and galvanostatic cycling was implemented at various charge-discharge current densities, cyclic voltammograms of Li-ions insertion/extraction processes were obtained and the Electrochemical Impedance Spectroscopy (EIS) was investigated. An exceptional cyclic stability and storage capacity for the V-doped maghemite was observed for low current density. The Mo-doped maghemite has higher capacity retention at high current densities.
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