Observation of the fastest chemical processes in the radiolysis of water

The “hole” story of water ionization The direct observation of the cationic hole H 2 O + that is formed in liquid water after ionization has been a long-standing experimental challenge. Previous attempts using optical and ultraviolet techniques have failed to reveal its key spectroscopic signature during ultrafast transformation into a OH radical. Loh et al. address this gap by using intense, ultrafast x-ray pulses from an x-ray free electron laser at ∼530 electron volts. They found compelling evidence for the formation H 2 O + and its decay to an OH radical by a proton transfer mechanism and elucidated the other fastest–time scale steps in the early-time dynamics of ionized liquid water. Science , this issue p. 179