Abstract The migration of zinc‐ion batteries from alkaline electrolyte to neutral or mild acidic electrolyte promotes research into their flexible applications. However, discharge voltage of many reported zinc‐ion batteries is far from satisfactory. On one hand, the battery voltage is substantially restricted by the narrow voltage window of aqueous electrolytes. On the other hand, many batteries yield a low‐voltage discharge plateau or show no plateau but capacitor‐like sloping discharge profiles. This impacts the battery's practicability for flexible electronics where stable and consistent high energy is needed. Herein, an aqueous zinc hybrid battery based on a highly concentrated dual‐ion electrolyte and a hierarchically structured lithium‐ion‐intercalative LiVPO 4 F cathode is developed. This hybrid battery delivers a flat and high‐voltage discharge plateau of nearly 1.9 V, ranking among the highest reported values for all aqueous zinc‐based batteries. The resultant high energy density of 235.6 Wh kg −1 at a power density of 320.8 W kg −1 also outperforms most reported zinc‐based batteries. A designed solid‐state and long‐lasting hydrogel electrolyte is subsequently applied in the fabrication of a flexible battery, which can be integrated into various flexible devices as powerful energy supply. The idea of designing such a hybrid battery offers a new strategy for developing high‐voltage and high‐energy aqueous energy storage systems.