材料科学
结晶
硅酸铝
成核
陶瓷
镧系元素
相(物质)
掺杂剂
Crystal(编程语言)
化学工程
兴奋剂
矿物学
离子
复合材料
光电子学
热力学
化学
工程类
物理
催化作用
有机化学
程序设计语言
生物化学
计算机科学
作者
Yongzhao Peng,Jiasong Zhong,Xinyue Li,Jiangkun Chen,Junjie Zhao,Xvsheng Qiao,Daqin Chen
标识
DOI:10.1016/j.jeurceramsoc.2018.12.036
摘要
Glass ceramic has been regarded as an alternative to traditional bulk materials such as single crystal and transparent ceramic. The nucleation/growth behavior of glass ceramic via crystallization is an important topic but is seldom studied so far. In the present work, a series of La3+-based oxyfluoride aluminosilicate glasses are designed to understand their nanocrystallization processes upon heating. Impressively, controllable LaF3, α-NaLaF4 and β-NaLaF4 phase-competitive crystallization in glasses is achieved and structural/spectroscopic characterizations confirm the key role of Al/Si ratio to determine the release of Na+ ions from glass network to participate in crystallization and phase transformation. Furthermore, the developed glass ceramics are evidenced to be ideal hosts for lanthanide dopants (such as Eu3+ and Yb3+/Er3+), which can effectively incorporate into the precipitated fluoride crystal lattices by substituting La3+ ions. As a consequence, incoherent LED-excitable upconverting devices are constructed to demonstrate their promising application as emitting media in display.
科研通智能强力驱动
Strongly Powered by AbleSci AI