Multiple Photoluminescent Processes from Pyrene Derivatives with Aggregation‐ and Mechano‐Induced Excimer Emission

Abstract Two novel pyrene‐based isocyanide gold(I) complexes have been designed and synthesized. The different structures lead to distinct and diverse photophysical properties both in solution and in the aggregate state. Multiple photoluminescence, involving monomer emission, locally excited emission and excimer emission, are observed. Notably, an excimer is formed by aggregation in solution and external mechanical stimulation in the solid state, showing aggregation‐ and mechano‐induced excimer emission.