二甲氧基乙烷
等压法
甲基环戊烷
化学
热力学
活度系数
汽液平衡
己烷
二进制数
非随机双液模型
二进制系统
物理化学
有机化学
色谱法
数学
电解质
水溶液
物理
算术
催化作用
铂金
电极
作者
Yinhai Sun,Dianliang Fu,Shugen Ma,Zhen Ma,Lanyi Sun
标识
DOI:10.1021/acs.jced.7b00802
摘要
Isobaric vapor–liquid equilibrium (VLE) data for binary systems of n-hexane + 1,2-dimethoxyethane and methylcyclopentane + 1,2-dimethoxyethane were measured at 101.3 kPa with an Ellis vapor–liquid equilibrium still, and the thermodynamic consistency of the experimental data was checked and passed by the Herington method and Wisniak test. The VLE values were correlated with the nonrandom two-liquid, universal quasichemical and Wilson activity coefficient models, and the corresponding binary interaction parameters of the three models were obtained. The results correlated with three models have good agreement with the experimental data, indicating that the three models were all fitted well.
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